DISPLAY OF UN NUMBERS ON VEHICLES, TANKS & CONTAINERS

In below cases the UN Number must be displayed on the Vehicles, Tanks or Containers

Tank Solids, liquids or gases transported (on each compartment of a multi-compartment tank)
Container When only one UN Number is loaded and it is having excess of 4,000 KG gross mass
Tanks Unpackaged LSA-I or SCO-I material of class 7
Vehicle Unpackaged LSA-I or SCO-I material of class 7
Container Unpackaged LSA-I or SCO-I material of class 7
Vehicle Packaged radioactive material with a single UN Number transported under exclusive use
Container Packaged radioactive material with a single UN Number transported under exclusive use
Bulk Container Solid dangerous goods

UN Number must be displayed in black digits not less than 65 mm high.

Example >>

WHEN DO WE NEED TO PROVIDE TECHNICAL NAMES

IMDG Code chapter 5.4, Documentation, states Proper Shipping Names that are assigned special provision 274 in Column 6 of the Dangerous Goods List shall be supplemented with their technical or chemical group names as described in 3.1.2.8.

Section 3.1.2.8 states ““Generic and “not otherwise specified” Proper Shipping Names that are assigned to special provision 274 or 318 in column 6 of the Dangerous Goods List shall be supplemented with the technical or chemical group names unless a national law or international convention prohibits its disclosure if it is a controlled substance.”

So we understand that when special provision 274 or 318 is assigned to any entry in Dangerous Goods List same must be provided with a technical name!

This is not the end of the requirement 😉 there is one more special provision which asks for technical names. This is SP 220 assigned to UN 3248 MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S

Note that UN 1851 MEDICINE, LIQUID, TOXIC, N.O.S. is not assigned with SP 220 only UN 3248 MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S is assigned with SP 220

SP 220 states that the technical name of flammable liquid component shall be shown in brackets immediately following the Proper Shipping Name.

IMSBC CODE – SHIPPER’S DECLARATION

Before loading of Solid Bulk Cargo the shipper must furnish information to the master or his representative about the cargo sufficiently in advance of loading to enable the precautions which may be necessary for proper stowage and safe carriage of the cargo to be put into effect.

A bulldozer is loaded on a bulk carrier using ...
A bulldozer is loaded on a bulk carrier using a crane, prior to unloading. Français : Un bulldozer est chargé sur un vraquier grâce à une grue, avant de commencer le déchargement. (Photo credit: Wikipedia)

Sample editable form is attached here.IMSBC DECLARATION

LIGHTERS or LIGHTER REFILLS

Lighters are pressurized article containing butane gas which is triggered to ignition by flint or piezoelectric ignition system. The design of the lighter is such that the ignition and release of flammable gas can only occur by action by the user and it cannot run into ignition when stored.

A partial profile view of the ignition system ...

There are two standards for lighters (1) ISO 9994:2002 and (2) European standard EN 13869:2002. European standard includes child-resistance specifications also.

Lighter refills are gas canisters to fill lighters exhausted its fuel.

Special provisions of transport regulations states

  • Lighters shall be provided with protection against inadvertent discharge.
  • The liquid portion of the gas shall not exceed 85% of the capacity of the receptacle at 15 °C.
  •  The receptacles, including the closures, shall be capable of withstanding an internal pressure of twice the pressure of the liquefied petroleum gas at 55 °C.
  •  The valve mechanisms and ignition devices shall be securely sealed, taped or otherwise fastened or designed to prevent operation or leakage of the contents during transport.
  •  Lighters shall not contain more than 10 g of liquefied petroleum gas.
  • Lighter refills shall not contain more than 65 g of liquefied petroleum gas

Lighters and Lighter refills are listed as UN 1057 class 2.1 in IMDG Code

COPIOUS QUANTITIES OF WATER

Hr.Ms. De Zeven Provinciën helps the Hyundai F...
Hr.Ms. De Zeven Provinciën helps the Hyundai Fortune (Photo credit: Wikipedia)

Emergency Response Procedures for Ships Carrying Dangerous Goods  (EmS Guide) states in its various schedules to use “copious quantities of water” for firefighting and handling spillage of dangerous goods.

For Example see fire schedule F-E below

 “Copious quantities of water” means total quantities of water provided for optimal fire-fighting using four jets of water, as required by SOLAS regulation II-2/4.

Nederlands: Het containerschip Hyundai Fortune...
Nederlands: Het containerschip Hyundai Fortune brandt als een fakkel. Op de achtergrond Hr. Ms. De Zeven Provinciën. (Photo credit: Wikipedia)

DANGEROUS GOODS WHICH REQUIRE SEGREGATION FROM FOODSTUFFS

Below dangerous goods require segregation from foodstuffs as “away from” or separated from”, look at the individual schedule for more details.

雞腿 腿
雞腿 腿 (Photo credit: Wikipedia)

UN 1111 AMYL MERCAPTANS

UN 1228 MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S.

UN 1228 MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S

UN 1369 p-NITROSODIMETHYLANILINE

UN 2210 MANEB or MANEB PREPARATION with not less than 60% maneb

UN 2212 BLUE ASBESTOS (crocidolite) or BROWN ASBESTOS (amosite, mysorite)

UN 2315 POLYCHLORINATED BIPHENYLS, LIQUID

UN 2347 BUTYL MERCAPTANS

UN 2363 ETHYL MERCAPTAN

UN 2402 PROPANETHIOLS

UN 2590 WHITE ASBESTOS (chrysotile, actinolite, anthophyllite, tremolite)

UN 2912 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA- I), non fissile or fissile-excepted

UN 2913 RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS( SCO-I or SCO-II), non fissile or fissile-excepted

UN 2915 RADIOACTIVE MATERIAL, TYPE A PACKAGE, non-special form, non fissile or fissile-excepted

UN 2916 RADIOACTIVE MATERIAL, TYPE B(U) PACKAGE, non fissile – or fissile-excepted

UN 2917 RADIOACTIVE MATERIAL, TYPE B(M) PACKAGE, non – fissile or fissile-excepted

UN 2919 RADIOACTIVE MATERIAL TRANSPORTED UNDER SPECIAL ARRANGEMENT, non fissile or fissile-excepted

UN 2968 MANEB, STABILIZED or MANEB PREPARATION, STABILIZED against self-heating

UN 2969 CASTOR BEANS or CASTOR MEAL or CASTOR POMACE or CASTOR FLAKE

UN 2977 RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, FISSILE

UN 2978 RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE non fissile or fissile-excepted

UN 2989 EAD PHOSPHITE, DIBASIC

UN 3054 CYCLOHEXANETHIOL (CYCLOHEXYL MERCAPTAN)

UN 3151 POLYHALOGENATED BIPHENYLS, LIQUID or POLYHALOGENATED TERPHENYLS, LIQUID

UN 3152 POLYHALOGENATED BIPHENYLS, SOLID or POLYHALOGENATED TERPHENYLS, SOLID

UN 3321 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA II), non fissile or fissile-excepted

UN 3322 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA III), non fissile or fissile-excepted

UN 3323 RADIOACTIVE MATERIAL, TYPE C PACKAGE, non fissile or fissile-excepted

UN 3324 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA- II), FISSILE

UN 3325 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY, (LSA- III), FISSILE

UN 3326 RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS (SCO-I or SCO-II), FISSLE

UN 3327 RADIOACTIVE MATERIAL, TYPE A PACKAGE, FISSILE, non special form

UN 3328 RADIOACTIVE MATERIAL, TYPE B(U) PACKAGE, FISSILE

UN 3329 RADIOACTIVE MATERIAL, TYPE B(M) PACKAGE, FISSILE

UN 3330 RADIOACTIVE MATERIAL, TYPE C PACKAGE, FISSILE

UN 3331 RADIOACTIVE MATERIAL, TRANSPORTED UNDER SPECIAL  ARRANGEMENT, FISSILE

UN 3332 RADIOACTIVE MATERIAL, TYPE A PACKAGE, SPECIAL FORM, non fissile or fissile-excepted

UN 3333 RADIOACTIVE MATERIAL, TYPE A PACKAGE, SPECIAL FORM, FISSILE

UN 3336 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S.

UN 3432 POLYCHLORINATED BIPHENYLS, SOLID

ETHYL MERCAPTAN

Liquefied Petroleum Gas
Liquefied Petroleum Gas (Photo credit: anarchytecture)

Ethyl Mercaptan is a highly flammable liquid having low boiling point of 35 Dec C and flashpoint below -45 Deg C (closed cup). This chemical, Ethyl Mercaptan, has a very unpleasant odor which Guinness Book of World Record identifies as the smelliest substance in the world.

Ethyl Mercaptan is added to LPG (Liquefied Petroleum Gas) intentionally to warn us when there is a leakage since we can immediately detect the bad smell of Ethyl Mercaptan.

In IMDG Code Ethyl Mercaptan is listed under UN 2363 Class 3 Packing Group I

AVIATION FUEL

A Shell Jet A refueller truck on the ramp at V...
A Shell Jet A refueller truck on the ramp at Vancouver International Airport. Image taken by me on July 7, 2005, and released under the GFDL. -Lommer (Photo credit: Wikipedia)

Aviation fuel is high-grade petroleum fuel having additives to reduce risk of icing or explosion due to high temperature.

Typical Jet fuel consists of Kerosene, Naphthalene, Ethyl Benzene,  Trimethyl Benzene, Diethylene Glycol Monomethyl Ether, Alkyl Dithiothiadiazole  where kerosene is the biggest constituent.

Shell Aviation fuel truck at Trondheim Airport...
Shell Aviation fuel truck at Trondheim Airport, Værnes (Photo credit: Wikipedia)

IMDG Code list aviation fuel under UN 1863 FUEL, AVIATION, TURBINE ENGINE Class 3

TRANSPORT OF WASTES

For sea transport wastes which are dangerous goods must be transported in accordance with the provisions of IMDG Code

Transboundary movement of waste is governed by “Basel Convention on the Control of Transboundary Movements of Hazardous Wastes and their Disposal (1989)”.

Before commencement of movement of waste from one country to another, competent authority of the origin country must sent notification to competent authority of country of destination. All parties involved, origin, destination and transit countries, shall approve the movement.

Together with dangerous goods declaration a waste movement document must also accompany the consignment.

Wastes which are not dangerous goods according to IMDG Code but covered under the Basel Convention may be transported under the class 9 entries for ENVIRONMENTALLY

HAZARDOUS SUBSTANCE, LIQUID, N.O.S., UN 3082, or ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., UN 3077.

BASEL MOVEMENT DOCUMENT

Blank world map, coloured as per the signatori...
Blank world map, coloured as per the signatories and ratification of the Basel Convention Blue = Signed and ratified Red = Signed, but not ratified Grey = Not a signatory (Photo credit: Wikipedia)

SEGREGATION OF DANGEROUS GOODS IN CONTAINERS

When there is a segregation requirement between dangerous goods both shall not be loaded together in a shipping container. However if the segregation requirement is “away from” each other then both may be loaded provided such consolidation is authorized my competent authority.