Dangerous Goods Transport Regulations

Below are various regulations concerning Dangerous Goods transport and chemicals

This is not an exhaustive list but a simple guidance to readers about some regulations currently in force.

Mode

Regulation

Description

Road

ADR

European Agreement concerning the International Carriage of Dangerous Goods by Road

Rail

RID

(Reglement concernant le transport International ferroviare des merchandises Dangereuses par chemin de fer (RID)  ) The regulations concerning the international carriage of dangerous goods by rail

River

ADN

European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways

River

ADNR

Rhine River

River

ADND

Danube River

Air

IATA TI

International Air Transport ( Technical Instructions )

U.S.A

CFR 49

Code of Federal Regulations 49 ( U.S.A. Road, Rail, Water, Air)

Canada

TDG

Transport of Dangerous Goods Canada

Australia

ADG

Australian Dangerous goods, Code Australia

Argentina, Brazil, Paraguay, and Uruguay + Venezuela going to become full member

MERCOSUR

 

Agreement on the Transport of Dangerous Goods in MERCOSUR

SEA

IMDG Code

International Maritime Dangerous Goods Code

GHS

Harmonizing all Regulations

The Globally Harmonized System of Classification and Labelling of Chemicals

China

 

Regulations  on safe management on hazardous chemicals China 2011

Other Conventions and Protocols

Montreal Protocol

 

Ozone Depleting Substances

The Montreal Protocol on Substances That Deplete the Ozone Layer (a protocol to the Vienna Convention for the Protection of the Ozone Layer) is an international treaty designed to protect the ozone layer by phasing out the production of numerous substances believed to be responsible for ozone depletion.

Bamako Convention

 

Hazardous Wastes within Africa 

Bamako Convention on the ban on the Import into Africa and the Control of Transboundary Movement and Management of Hazardous Wastes within Africa  is a treaty of African nations prohibiting the import of any hazardous (including radioactive) waste

Rotterdam Convention

 

Hazardous Chemicals and Pesticides

The Rotterdam Convention on the Prior Informed Consent Procedure for Certain Hazardous Chemicals and Pesticides in International Trade, more commonly known simply as the Rotterdam Convention, is a multilateral treaty to promote shared responsibilities in relation to importation of hazardous chemicals.

Stockholm Convention

 

Persistent Organic Pollutants

Stockholm Convention on Persistent Organic Pollutants is an international environmental treaty that aims to eliminate or restrict the production and use of persistent organic pollutants (POPs).

Basel Convention

 

Waste

The Basel Convention on the Control of Transboundary Movements of Hazardous Wastes and Their Disposal, usually known simply as the Basel Convention, is an international treaty that was designed to reduce the movements of hazardous waste between nations, and specifically to prevent transfer of hazardous waste from developed to less developed countries (LDCs).

Australia Group

Dual Use Chemicals

The Australia Group is an informal group of countries (now joined by the European Commission) established in 1985 (after the use of chemical weapons by Iraq in 1984) to help member countries to identify those of their exports which need to be controlled so as not to contribute to the spread of chemical and biological weapons

WHO

Pesticides

The WHO Recommended Classification of Pesticides by Hazard and Guidelines to Classification 2009

UN Package Markings & Tests

Jerrycans.
Jerrycans

Packaging means one or more receptacles and any other components or materials necessary
for the receptacles to perform their containment and other safety functions
.

Package means the complete product of the packing operation, consisting of the packaging and its contents prepared for transport.

Below is for beginners to understand what do Packing Codes means and why do some shipping lines or freight forwarders ask for it.

As per IMDG Code the design of each packaging used for carriage of Dangerous Goods shall pass  UN Performance testing. (Consignments of Dangerous goods in limited quantities does not require this ) Details of performance test for various types of packaging are laid out in Chapter 6 of IMDG Code.

After the performance test a unique marking will be issued by the testing authority which shall be durable and legible.

If the packaging is intended to carry gross mass of more than 30 Kg of then this marking is required to be on the top or on the side of the packaging.

For Packaging of more than 30 kg the letters, numerals and symbols shall be at least 12mm high.

For Packaging of 30 kg, 30 l or less the letters, numerals and symbols shall be at least 6mm high.

For Packaging of 5kg, 5 l or less the letters, numerals and symbols shall be of appropriate size.

Packaging Marks

Each package design type is tested and issued with a unique mark from which we can understand the type of package and certain other details.

The code consists of:
.1 an Arabic numeral indicating the kind of packaging, such as drum, jerrican, etc.,
followed by

.2 one or more capital letters in Latin characters indicating the nature of the material,
such as steel, wood, etc., followed where necessary by

.3 an Arabic numeral indicating the category of packaging within the type to which the
packaging belongs.

Kind of Packaging

1 Drum
2 (Reserved)
3 Jerrican
4 Box
5 Bag
6 Composite packaging

Types of material:
A Steel (all types and surface treatments)
B Aluminium
C Natural wood
D Plywood
F Reconstituted wood
G Fibreboard
H Plastics material
L Textile
M Paper, multiwall
N Metal (other than steel or aluminium)

Lets look at an example package marking and interpret same to understand how this works

image

Letters UN = United Nations Symbol

4G = Packaging Code ( 4= box , G = Fibreboard )

Y = Tested for packing group II

145 = Maximum gross mass in Kilogram

S = Packing intended to carry solids or inner packing

02 = Last two digits of the year in which packaging was manufactured

NL = The country authorizing the allocation of this mark

VL823 = Manufacturer’s details

Testing

These design types  of packaging undergo various types of test as required by the IMDG Code. Lets look at some of the test requirements

Drop test for Bag

Packaging No. of test samples Drop orientation
Bags – single-ply with a side seam Three
(three drops per
bag)
First drop: flat on a wide face
Second drop: flat on a narrow face
Third drop: on the end of the bag
Bags – single-ply without a side
seam or multi-ply
Three
(two drops per bag)
First drop: flat on a wide face
Second drop: on an end of the bag

Drop height

Packing group I

Packing group II Packing group III
1.8m 1.2m 0.8m

if the substance  to be carried have a relative density more than 1.2 then the drop height is calculated as

dx1.5m , dx1.0m & dx0.67m for packing groups I,II and III respectively.

Leakproofness test

Any packaging intended to carry liquids shall undergo leakproofness test. These packaging will be kept under water and internal air pressure is applied

Packing group I

Packing group II Packing group III
Not less than
30 kPa (0.3 bar)
Not less than
20 kPa (0.2 bar)
Not less than
20 kPa (0.2 bar)

After conducting various test, as specified in chapter 6 of IMDG Code on successful pass a certificate will be issued by the testing authority to the manufacturer of packaging with below mandatory details

  1. name and address of the test facility;
  2. name and address of applicant (where applicable);
  3. a unique test report identification;
  4. date of the test report;
  5. manufacturer of the packaging;
  6. description of the packaging design type (such as dimensions, materials, closures,
    thickness, etc.), including method of manufacture (such as blow-moulding), and which
    may include drawing(s) and/or photograph(s);
  7. maximum capacity;
  8. characteristics of test contents, such as viscosity and relative density for liquids and
    particle size for solids;
  9. test descriptions and results;
  10. signature, with the name and status of the signatory.

This mark on the packaging does not necessarily confirm that the packaging may be used for any substance. For type of packaging and quantity of dangerous goods in packaging one must look into specific entry in chapter 3 and find out what type of packaging is allowed and what is the max allowed mass or quantity per package.

Quantity of Dangerous Goods

Gravity at a macroscopic level.
Image via Wikipedia

 Mass and Weight

Mass and weight are two different things though the word weight is used many occasions in the place of mass. Every object has a mass. It never changes. An object having a mass of 50 Kg will have the same mass whether it is on the surface of Earth or Moon.

Weight is used to describe the mass of the body or the force of the gravity acting on it. Actually weight is the measure of gravitational force acting on the object at a specific location. Tthe object with the mass of 50 kg will have the weight of 50 kgf on the surface of the Earth but only 8.5 kgf on the surface of the moon.

Effects by change of gravity

Now we know that change of gravity will have dynamic effect on the weight.  A shipping container falling downwards with an acceleration force greater than 9.8m/sec will make the mass weight less. However move the container at same speed upwards will make the weight of the mass double.

During ocean passage the movements of the vessel will make considerable changes to the weight of the cargo within the containers.

A well secured cargo in container not only minimizes cargo damage and claim but will drastically minimize hazard due to shifting of cargo or leakage which can be fatal in case of dangerous goods.

Vessel’s motions at sea

What shall be declared for dangerous goods?  Mass? Weight? Net or Gross?

Quantity of Dangerous goods shall be declared by volume or mass as appropriate.

Gross mass              = mass of dangerous goods and package

Net mass                  = mass of dangerous goods

In IMDG Code whenever the mass of a package is mentioned, the gross mass is meant. However this does not include mass of tanks and containers.

Example of declaration

UN 1263 PAINT class 3 PG III (24 Deg C.c.c)  1 x steel drum 100 kg

UN 1263 PAINT class 3 PG III (24 Deg C.c.c)  1 x steel drum Gross mass 100 kg net mass 93 kg

Filling of packages

While filling of packages the quantity allowed is given in volume or by mass in IMDG Code. See example packing instruction below.

For gas it is altogether different case because there we deal with pressure 🙂