Dangerous Goods Transport Information

In the last article we looked at hazard communication through marks and labels on packages. This type of visual communication, marks, labels on packages and placards on containers, is addressing only those who are in the vicinity of packages/containers or handling them. More detailed communication throughout the transport chain takes place through “Dangerous Goods Declaration”, here in after referred as DGD.

For every consignment of Dangerous Goods, ‘Dangerous Goods Transport Information’ must be provided. This is a requirement as per Regulation 4 of SOLAS Chapter VII Part A and Regulation 4 of MARPOL 73/78, Annex III. There are exceptions for certain goods.

The most important function of transport document is to convey the information about hazardous goods consigned. Shipper can submit this document/information either as a hard copy or through electronic data processing (EDP) and electronic data interchange (EDI) transmission techniques.

Five Elements of Dangerous Goods description:

  1. The UN Number preceded by the letters “UN”;
  2. The Proper Shipping Name including the technical name enclosed in parenthesis, as applicable;
  3. The primary hazard class or, when assigned, the division of the goods, including, for class 1, the compatibility group letter;
  4. Subsidiary hazard class or division number(s) corresponding to the subsidiary risk label(s) required to be applied, when assigned, shall be entered following the primary hazard class or division and shall be enclosed in parenthesis;
  5. Where assigned, the packing group for the substance or article.

The sequence of above 5 elements must always be written in the order 1, 2, 3, 4 and 5, it must never be scattered or placed here and there in the DGD.

In order to provide exact nature of the dangerous goods Proper Shipping Name must be supplemented as below.

  1. For goods assigned with Special Provisions 278 or 318 Proper Shipping Name shall be supplemented with technical names or chemical group names.
  2. Placing the words EMPTY UNCLEANED” or “RESIDUE LAST CONTAINED” for packagings, IBCs, bulk containers, tanks, road tank vehicles or railway tank wagons which contain the residue of dangerous goods. This must be placed either before or after the dangerous goods descriptions as per 1 to 5 above and is not applicable for Class 7 Radioactive materials.
  3. All waste goods, other than Class 7 Radioactive wastes, Proper Shipping Name shall be supplemented with the word “WASTE” unless this is already part of Proper Shipping Name.
  4. When liquid is transported at temperature equal to or exceeding 100°C or solids equal to or exceeding 240°C and the Proper Shipping Name does not convey the elevated temperature condition then the word “HOT” shall precede the Proper Shipping Name.
  5. If the goods are marine pollutant then it must be identified by the term “MARINE POLLUTANT” or “MARINE POLLUTANT / ENVIRONMENTALLY HAZARDOUS”
  6. If the dangerous goods to be transported have a flashpoint of 60°C or below (in °C closedcup (c.c.)), the minimum flashpoint shall be indicated.

Examples

UN 1098   ALLYL ALCOHOL 6.1 (3) I (21°C c.c.)

UN 1098, ALLYL ALCOHOL, class 6.1, (class 3), PG I, (21°C c.c.)

UN 1092, Acrolein, stabilized, class 6.1 (3), PG I, (–24°C c.c.) MARINE POLLUTANT/ENVIRONMENTALLY HAZARDOUS

UN 2761, Organochlorine pesticide, solid, toxic, (Aldrin 19%), class 6.1, PG III, MARINE POLLUTANT

The total quantity of Dangerous Goods must be declared in mass or volume as appropriate. This must be declared separately for each Proper Shipping Name with different UN Number or Packaging Group. The number and type of packages must also be declared, however, no need to declare the quantity by mass or volume for empty uncleaned packaging. Estimated quantity need to be declared for salvage packaging. For dangerous goods in tanks the gross mass does not include the tare weight. Package type can be declared as drums or boxes but most carriers insist to declare full description. Example; Steel non removable head drums.

In the multimodal transport the goods need to comply with regulations applicable to all modes of transport it goes through as well the country specific requirements. The certification by consignor acknowledges same.

“I hereby declare that the contents of this consignment are fully and accurately described above by the Proper Shipping Name, and are classified, packaged, marked and labelled/placarded, and are in all respects in proper condition for transport according to applicable international and national government regulations.”

By certifying above, a consignment is guaranteed to meet all international and national regulatory norms.

When goods are packed in a container the packer need to issue a container packing certificate. This can be together with the Dangerous Goods Declaration in the same form or separate.

Signature of the persons responsible can be replaced by name in capital letters when DGD is submitted through electronic medium (EDI or EDP). Language of the DGD can be Swahili, Bhojpuri, Mandarin, or any other language, however, the carrier demand the DGD in a language they prefer.

Together with DGD additional documents also may be required which is prompted by individual entries and other requirements of IMDG Code. To correctly fill up a DGD one must be trained to do so. It is illegal for anyone to prepare a DGD without receiving training.

Above is just the basic information, there are many more requirements as applicable to various goods which can be found in chapter 5.4 of IMDG Code and individual schedules.

You may download the DGD format from http://tinyurl.com/m4wcvhg

Further reading: Documentary Aspects of the International Transport of Dangerous Goods, Revised Recommendation No. 11, ECE/TRADE/C/CEFACT/2008/8

SP 274 the ‘What’ and ‘Whys’ of Technical Names

Special Provision 274 assigned to Generic and Not Otherwise Specified (N.O.S.) entries in Model Regulations requires the shipper to supplement the Proper Shipping Name (PSN) with Technical Name on the Packages (marking) and in shipping papers (Dangerous Goods Declaration).

 ‘What’ must supplement the proper shipping name and ‘Why’ this is required.

What

The Generic and N.O.S. entries assigned with SP 274 shall be supplemented with

  • Technical or Chemical group names
  • Shall be a recognized chemical or other name currently used in scientific and technical handbooks, journals and texts.
  • Shall be entered in brackets immediately following the Proper Shipping Name
  • Modifier, such as “contains” or “containing” or other qualifying words such as “mixture”, “solution”, etc., and the percentage of the technical constituent may also be used
  • Trade names shall not be used for this purpose

 For Pesticides below may be used:

  • ISO common name(s),
  • other name(s) in the WHO Recommended Classification of Pesticides by Hazard and Guidelines to Classification
  • the name(s) of the active substance(s)

When not required?

When a national law or international convention prohibits disclosing the name of a controlled substance.

Why Technical name is required?

Below table shows some of the reasons for the requirement of technical names through special provision 274

 

LOGIC OF TECHNICAL NAME UNDER SP 274 - UN MODEL REGULATIONS
LOGIC OF TECHNICAL NAME UNDER SP 274 – UN MODEL REGULATIONS
  • Example: UN 1993 Flammable liquid, n.o.s. (contains xylene and benzene)

 

This article is in accordance with 37th amendment of IMDG Code.

Acids and Alkalis ( IMDG 35-10)

Most viewed topic under segregation on this site is Acids and Alkalis. Most of the Acids and Alkalis fall under Class 8 ; this makes it imperative that we must look in Column 16 of DGL to check the segregation requirements.

Acids and Alkalis are not allowed to be packed in the same outer packaging or stowed in the same container.

When both Acids and Alkalis belongs to class 8 they may be kept together under below clauses of IMDG Code

  1. Limited Quantities different Packaging  – No Segregation applicable
  2. Excepted Quantities different Packaging – No Segregation applicable
  3. Same outer packing or same container – As per 7.2.1.13.2 of IMDG Code
  4. Same outer packing in Limited Quantities -As per 3.4.4.1.2 of IMDG Code

Refer 5.4.1.5.2.2 & 5.4.1.5.11.3 of IMDG Code for dangerous goods declaration of Acid and Alkali consolidation.

For quick reference both Acids and Alkalis in 35th Amendment of IMDG Code is listed below

* indicates strong acids

ACIDS

ALKALIS

UN No.

Proper Shipping Name

UN No.

Proper Shipping Name

1052

Hydrogen fluoride, anhydrous*

1005

Ammonia, anhydrous

1182

Ethyl chloroformate

1160

Dimethylamine, aqueous solution

1183

Ethyldichlorosilane

1163

Dimethylhydrazine, unsymmetrical

1238

Methyl chloroformate

1235

Methylamine, aqueous solution

1242

Methyldichlorosilane

1244

Methylhydrazine

1250

Methyltrichlorosilane

1382

Potassium sulphide, anhydrous or potassium sulphide with less than 30% water of crystallization

1295

Trichlorosilane

1385

Sodium sulphide, anhydrous or sodium sulphide with less than 30% water of crystallization

1298

Trimethylchlorosilane

1604

Ethylenediamine

1305

Vinyltrichlorosilane

1719

Caustic alkali liquid, n.o.s

1572

Cacodylic acid

1813

Potassium hydroxide, solid

1595

Dimethyl sulphate

1814

Potassium hydroxide, solution

1715

Acetic anhydride

1819

Sodium aluminate solution

1716

Acetyl bromide

1823

Sodium hydroxide, solid

1717

Acetyl chloride

1824

Sodium hydroxide solution

1718

Butyl acid phosphate

1825

Sodium monoxide

1722

Allyl chloroformate

1835

Tetramethylammonium hydroxide solution

1723

Allyl iodide

1847

Potassium sulphide, hydrated with not less than 30% water of crystallization

1724

Allyltrichlorosilane, stabilized

1849

Sodium sulphide, hydrated with not less than 30% water

1725

Aluminium bromide, anhydrous

1907

Soda lime with more than 4% sodium hydroxide

1726

Aluminium chloride, anhydrous

1922

Pyrrolidine

1727

Ammonium hydrogendifluoride, solid

2029

Hydrazine, anhydrous

1728

Amyltrichlorosilane

2030

Hydrazine, aqueous solution with more than 37% hydrazine, by mass

1729

Anisoyl chloride

2033

Potassium monoxide

1730

Antimony pentachloride, liquid

2073

Ammonia solution relative density less than 0.880 at 15 °C in water, with more than 35% but not more than 50% ammonia

1731

Antimony pentachloride solution

2079

Diethylenetriamine

1732

Antimony pentafluoride

2259

Triethylenetetramine

1733

Antimony trichloride

2270

Ethylamine, aqueous solution, with not less than 50% but not more than 70% ethylamine

1736

Benzoyl chloride

2318

Sodium hydrosulphide with less than 25% water of crystallization

1737

Benzyl bromide

2320

Tetraethylenepentamine

1738

Benzyl chloride

2379

1,3-Diemthylbutylamine

1739

Benzyl chloroformate

2382

Dimethylhydrazine, symmetrical

1740

Hydrogendifluorides, n.o.s.

2386

1-Ethylpiperidine

1742

Boron trifluoride acetic acid complex, liquid

2399

1-Methylpiperidine

1743

Boron trifluoride propionic acid complex, liquid

2401

Piperidine

1744

Bromine or bromine solution

2491

Ethanolamine or ethanolamine solution

1745

Bromine pentafluoride

2579

Piperazine

1746

Bromide trifluoride

2671

Aminopyridines

1747

Butyltrichlorosilane

2672

Ammonia solution relative density between 0.880 and 0.957 at 15 °C in water, with more than 10% but not more than 35% ammonia, by mass

1750

Chloroacetic acid solution

2677

Rubidium hydroxide solution

1751

Chloroacetic acid, solid

2678

Rubidium hydroxide, solid

1752

Chloroacetyl chloride

2679

Lithium hydroxide solution

1753

Chlorophenyltrichlorosilane

2680

Lithium hydroxide

1754

Chlorosulphonic acid (with or without sulphur trioxide)

2681

Caesium hydroxide solution

1755

Chromic acid solution

2682

Caesium hydroxide

1756

Chromic fluoride, solid

2683

Ammonium sulphide solution

1757

Chromic fluoride solution

2733

Amines, flammable, corrosive, n.o.s. or polyamines, flammable, corrosive,n.o.s

1758

Chromium oxychloride

2734

Amines, liquid, corrosive, flammable, n.o.s. or polyamines, liquid, corrosive, flammable, n.o.s.

1762

Cyclohexenyltrichlorosilane

2735

Amines, liquid, corrosive, n.o.s. or polyamines, liquid, corrosive, n.o.s.

1763

Cyclohexyltrichlorosilane

2795

Batteries, wet, filled with alkali electric storage

1764

Dichloroacetic acid

2797

Battery fluid, alkali

1765

Dichloroacetyl chloride

2818

Ammonium polysulphide solution

1766

Dichlorophenyltrichlorosilane

2949

Sodium hydrosuonlphide, solid with not less than 25% water of crystallizati

1767

Diethyldichlorosilane

3028

Batteries, dry, containing potassium hydroxide, solid electric storage

1768

Difluorophosphoric acid, anhydrous

3073

Vinylpyridines, stabilized

1769

Diphenyldichlorosilane

3253

Disodium trioxosilicate

1770

Diphenyl methylbromide

3259

Amines, solid, corrosive, n.o.s. or polyamines, solid, corrosive, n.o.s.

1771

Dodecyltrichlorosilane

3262

Corrosive solid, basic, inorganic, n.o.s

1773

Ferric chloride, anhydrous

3263

Corrosive solid, basic, organic, n.o.s

1775

Fluoroboric acid

3266

Corrosive liquid, basic, inorganic, n.o.s

1776

Fluorophosphoric acid, anhydrous

3267

Corrosive liquid, basic, organic, n.o.s

1777

Fluorosulphonic acid*

3293

Hydrazine, aqueous solution with not more than 37% hydrazine, by mass

1778

Fluorosilicic acid

3318

Ammonia solution relative density less than 0.880 at 15 °C in water, with  more than 50% ammonia

1779

Formic acid with more than 85% acid by mass

3320

Sodium borohydride and sodium hydroxide solution with not more than 12% sodium borohydride and not more than 40% sodium hydroxide, by mass

1780

Fumaryl chloride

3423

Tetramethylammonium hydroxide, solid

1781

Hexadecyltrichlorosilane

3484

Hydrazine aqueous solution, flammable, with more than 37% hydrazine, by mass

1782

Hexafluorophosphoric acid

1784

Hexyltrichlorosilane

1786

Hydrofluoric acid and sulphuric acid mixture*

1787

Hydriodic acid*

1788

Hydrobromic acid*

1789

Hydrochloric acid*

1790

Hydrofluoric acid*

1792

Iodine monochloride

1793

Isopropyl acid phosphate

1794

Lead sulphate with more than 3% free acid

1796

Nitrating acid mixture*

1798

Nitrohydrochloric acid*

1799

Nonyltrichlorosilane

1800

Octadecyltrichlorosilane

1801

Octyltrichlorosilane

1802

Perchloric acid with not more than 50% acid, by mass*

1803

Phenolsulphonic acid, liquid

1804

Phenyltrichlorosilane

1805

Phosphoric acid, solution

1806

Phosphorus pentachloride

1807

Phosphorus pentoxide

1808

Phosphorus tribromide

1809

Phosphorus trichloride

1810

Phosphorus oxychloride

1811

Potassium hydrogendifluoride, solid

1815

Propionyl chloride

1816

Propyltrichlorosilane

1817

Pyrosulphuryl chloride

1818

Silicon tetrachloride

1826

Nitrating acid mixture, spent*

1827

Stannic chloride, anhydrous

1828

Sulphur chlorides

1829

Sulphur trioxide, inhibited or sulphur trioxide, stabilized

1830

Sulphuric acid with more than 51% acid*

1831

Sulphuric acid, fuming*

1832

Sulphuric acid, spent*

1833

Sulphurous acid

1834

Sulphuryl chloride

1836

Thionyl chloride

1837

Thiophosphoryl chloride

1838

Titanium tetrachloride

1839

Trichloroacetic acid

1840

Zinc chloride solution

1848

Propionic acid with not less than 10% and less than 90% by mass

1873

Perchloric acid with more than 50% but not more than 72% acid, by mass*

1898

Acetyl iodide

1902

Diisooctyl acid phosphate

1905

Selenic acid

1906

Sludge acid*

1938

Bromoacetic acid solution

1939

Phosphorus oxybromide

1940

Thioglycolic acid

2031

Nitric acid, other than red fuming*

2032

Nitric acid, red fuming*

2214

Phthalic anhydride with more than 0.05% of maleic anhydride

2215

Maleic anhydride

2218

Acrylic acid, inhibited

2225

Benzenesulphonyl chloride

2226

Benzotrichloride

2240

Chromosulphuric acid*

2262

Dimethylcarbamoyl chloride

2267

Dimethyl thiophosphoryl chloride

2305

Nitrobenzenesulphonic acid

2308

Nitrosylsulphuric acid, liquid*

2331

Zinc chloride, anhydrous

2353

Butyryl chloride

2395

Isobutyrylchloride

2407

Isopropyl chloroformate

2434

Dibenzyldichlorosilane

2435

Ethylphenyldichlorosilane

2437

Methylphenyldichlorosilane

2438

Trimethylacetyl chloride

2439

Sodium hydrogendifluoride

2440

Stannic chloride pentahydrate

2442

Trichloroacetyl chloride

2443

Vanadium oxytrichloride

2444

Vanadium tetrachloride

2475

Vanadium trichloride

2495

Iodine pentafluoride

2496

Propionic anhydride

2502

Valeryl chloride

2503

Zirconium tetrachloride

2506

Ammonium hydrogen sulphate

2507

Chloroplatinic acid, solid

2508

Molybdenum pentachloride

2509

Potassium hydrogen sulphate

2511

2-Chloropropionic acid

2513

Bromoacetyl bromide

2531

Methacrylic acid, stablilized

2564

Trichloroacetic acid solution

2571

Alkylsulphuric acids

2576

Phosphorus oxybromide, molten

2577

Phenylacetyl chloride

2578

Phosphorus trioxide

2580

Aluminium bromide solution

2581

Aluminium chloride solution

2582

Ferric chloride solution

2583

Alkylsulphonic acids, solid or arylsulphonic acids, solid with more than 5% free sulphuric acid

2584

Alkylsulphonic acids, liquid or arylsulphonic acids, liquid with more than 5% free sulphuric acid

2585

Alkylsulphonic acids, solid or arylsulphonic acids, solid with not more than 5% free sulphuric acid

2586

Alkylsulphonic acids, liquid or arylsulphonic acids, liquid with not more than 5% free sulphuric acid

2604

Boron trifluoride diethyl etherate

2626

Chloric acid, aqueous solution with not more than 10% chloric acid

2642

Fluoroacetic acid

2670

Cyanuric chloride

2691

Phosphorus pentabromide

2692

Boron tribromide

2698

Tetrahydrophthalic anhydrides with more than 0.05 % of maleic anhydride

2699

Trifluoroacetic acid

2739

Butyric anhydride

2740

n-Propyl chloroformate

2742

Chloroformates, toxic, corrosive, flammable, n.o.s.

2743

n-Butyl chloroformate

2744

Cyclobutyl chloroformate

2745

Chloromethyl chloroformate

2746

Phenyl chloroformate

2748

2-Ethylhexyl chloroformate

2751

Diethylthiophosphoryl chloride

2789

Acetic acid, glacial or acetic acid solution, more than 80% acid, by mass

2790

Acetic acid solution, more than 10% but not more than 80% acid, by mass

2794

Batteries, wet filled with acid electric storage

2796

Sulphuric acid with not more than 51% acid or battery fluid, acid*

2798

Phenylphosphorus dichloride

2799

Phenylphosphorus thiodichloride

2802

Copper chloride

2817

Ammonium hydrogendifluoride solution

2819

Amyl acid phosphate

2820

Butyric acid

2823

Crotonic acid, solid

2826

Ethyl chlorothioformate

2829

Caproic acid

2834

Phosphorous acid

2851

Boron trifluoride dehydrate

2865

Hydroxylamine sulphate

2869

Titanium trichloride mixture

2879

Selenium oxychloride

2967

Sulphamic acid

2985

Chlorosilanes, flammable, corrosive, n.o.s.

2986

Chlorosilanes, corrosive, flammable, n.o.s.

2987

Chlorosilanes, corrosive, n.o.s.

2988

Chlorosilanes, water-reactive, flammable, corrosive, n.o.s.

3246

Methanesulphonyl chloride

3250

Chloroacetic acid, molten

3260

Corrosive solid, acidic, inorganic, n.o.s.

3261

Corrosive solid, acidic, organic, n.o.s.

3264

Corrosive liquid, acidic, inorganic, n.o.s.

3265

Corrosive liquid, acidic, organic, n.o.s.

3277

Chloroformates, toxic, corrosive, n.o.s.

3361

Chlorosilanes, toxic, corrosive, n.o.s.

3362

Chlorosilanes, toxic, corrosive, flammable, n.o.s.

3412

Formic acid with not less than 10% but not more than 85% acid by mass

3412

Formic acid with not less than 5% but not more than 10% acid by mass

3419

Boron trifluoride acetic acid complex, solid

3420

Boron trifluoride propionic acid complex, solid

3421

Potassium hydrogendifluoride solution

3425

Bromoacetic acid, solid

3453

Phosphoric acid, solid

3456

Nitrosylsulphuric acid, solid

3463

Propionic acid with not less than 90% acid by mass

3472

Crotonic acid, liquid

Amendment to SOLAS chapter VII – Regulation 4

At 90thsession held from 16 to 25 May 2012 Maritime Safety Committee (MSC) adopted amendment to SOLAS chapter VII – Regulation 4. The new text will replace the existing text and will come in force from 1 January 2014.

PSC inspection of motor vessel Union Anton
PSC inspection of motor vessel Union Anton (Photo credit: U.S. Coast Guard)

New text is as below

Regulation 4 –   Documentation

 1 Transport information relating to the carriage of dangerous goods in packaged form and the container/vehicle packing certificate shall be in accordance with the relevant provisions of the IMDG Code and shall be made available to the person or organization designated by the port State authority.

2 Each ship carrying dangerous goods in packaged form shall have a special list, manifest or stowage

plan setting forth, in accordance with the relevant provisions of the IMDG Code, the dangerous goods on board and the location thereof. A copy of one of these documents shall be made available before departure to the person or organization designated by the port State authority.

Regulation 4 is envisaged entry-into-force date of 1 January 2014, in order to align the entry-into-force date of the aforementioned SOLAS amendments with that of the amendments to the IMDG Code scheduled to be adopted in 2012

Intermediate Bulk Containers – Tests & Dates

Metal, rigid plastics and composite IBC intended to carry dangeroys goods by sea shall be inspected and tested*

  1. Before their first use
  2. Every two and a half and five years
  3. After repair or remanufacture, before reuse

After the date of expiry of last inspection an IBC shall not be used for transport.

But may be transported if

1.   Filled prior to the date of expiry of the last periodic test or inspection for a period not to exceed three months beyond the date of expiry of the last periodic test or inspection.

2. After emptying but before cleaning, for purposes of performing the required test or inspection prior to refilling

3. Unless otherwise approved by the competent authority, for a period not to exceed six months beyond the date of expiry of the last periodic test or inspection in order to allow the return of dangerous goods or residues for proper disposal or recycling.

Transport after date of expiry of last inspection need to be shown in the dangerous goods declaration.

*Five Years tests

1.  Conformity to the design type, including marking;

2.  Internal and external condition; and

3.  Proper functioning of service equipment.

*Two and a half years tests

  1.  External condition; and
  2.  Proper functioning of service equipment.

Further tests may be applicable – refer relevant sections of IMDG Code

Segregation Group on DGD

There are total 18 groups of segregation listed in IMDG Code section 3.1.4.4 starting with Group 1 Acid till Group 18 Alkali.

In case if a shipper decides to assign a substance, mixture, solutions or preparation under  an N.O.S. entry, which is not listed in segregation groups as mentioned in the paragraph above, to a particular segregation group then she or he shall include this information in dangerous goods declaration.

This shall be done with the appropriate segregation group name preceded by the phrase “IMDG Code segregation group”

Example:
UN 1760 CORROSIVE LIQUID, N.O.S. (Phosphoric acid, acetic acid) 8 III IMDG Code segregation group – 1 Acids

English: A segregation table as used in the IM...

CFR 49 Additional requirements

Below are some additional requirements in Dangerous Goods Declaration (Shipping Papers) as per 49 CFR (Code of Federal Regulations, 49).

English: Code of Federal Regulations, seen at ...

49 CFR is U.S.A specific transport regulations & part 100-185 of 49 CFR deals with dangerous goods transport by Road (highway), Rail, Air and Sea. This is based on UN Model regulations and is almost harmonized with other model regulations.

Requirement

UN Number

49 CFR Section

Description

Ex Number 3268Air bag inflator, Air bag module, or Seat-belt pre-tensioner 173.166 Air bag inflators, air bag modules and seat-belt pretensioners classified under UN 3268 must be approved by Associated administrator who will issue an EX number upon satisfaction of the requirements. Shipping paper must contain this EX Number or product code of each approved inflator, module or pretensioner together with other mandatory details required by the shipping paper. Ex Number or product code is not required to be marked on the packages
T- Number/ LAA Numbers
1057

( LIGHTERS)

49 CFR 173.308 (C) A test report identifier, that is, the authorized person or agency identifier code immediately followed by an alpha/numeric identifier of four or more characters assigned to the specific lighter design by the authorized person or agency (e.g., “LAA****,” where, “LAA” is the identification code assigned to the authorized person or agency by the Associate Administrator and “****” is replaced with the unique test report identifier assigned to the specific lighter design by the authorized person or agency);
Transitional provisions. Until January 1, 2012, approval numbers issued by the Associate Administrator prior to January 1, 2007 may continue to be marked on packages and annotated on shipping papers, where applicable. After that time, previously issued approvals (i.e., T-***) will no longer be valid and each lighter design currently in production must be re-examined and tested under the provisions of this section.
RQ
Reportable Quantity
Various Appendix to 49 CFR 172.101 When quantity in package equals or increases the quantity specified in Appendix to 49 CFR 172.101 shipping paper must contain letters “RQ” either before or after the basic description of dangerous goods.Please refer special provisions and related section of 49 CFR for full details. Click here to look up Reportable Quantity for a substance.
PIH
“Poison-Inhalation Hazard” or “Toxic-Inhalation Hazard”
Mostly Class 2.3, 6.1 and some Materials in 8 (HMT Column 7 and 172.102) In column 7 of Hazardous Material table if 1.2.3.4. or 5 is mentioned then poison inhalation hazard zone must be identified on the shipping paper.1 = Zone A2 = Zone B3 = Zone C

4 = Zone D

 

Emergency Response Number All 172.201(d), 172.604 Emergency contact Telephone number must be entered as “EMERGENCY CONTACT: xxx-xxx-xxxx” (include international access code if applicable).
Special Permits and Exemptions As applicable If the shipment is under any special permit or exemption then same must be entered on Shipping Paper (“DOT-SPxxxxx” or “DOT-Exxxxx” Special Permit or Exemption number)

Please refer to latest 49 CFR for full details of these requirements.

Face wipes

There are plenty of brands in market with face wipes (wet wipes); some for oily skin some for moisturizing etc. In this article we will look at two of these products and their transport classification as per IMDG Code.

  1. Clearasil Daily Care Deep Cleansing Wipes &

Both are cleansing wet wipes but one of this needs to be transported as dangerous goods if consigned as cargo by sea.

To understand the difference we will look at the ingredients of each of these products

1. Clearasil Daily Care Deep Cleansing Wipes
2. Clearasil Ultra Deep Pore Face Wipes
Ingredients Water, Propylne Glycol. Polysorbate 20, PEG-40 Hydrogenated Castor Oil. Malic Acid, Glycolic Acid, Lactic Acid, Pyrus Malus, Dichlorobenzyl Alcohol, Cetypyridinuim Chloride, Disodium EDTA, Citric Acid, Sodium Citrate, Phenoxyethanol, Benzoic Acid, Dehydroacetic Acid. Hydrogen Peroxide, Ethanol, Salicylic Acid, and other inert ingredients.

Product 1 Clearasil Daily Care Deep Cleansing Wipes

All the ingredients combined with the percentage does not have any properties of danger according to IMDG Code classification. This product does not have properties of explosives, flammable liquids or solids, oxidizing substances, toxicity, radioactivity or corrosive effect hence product one when offered as cargo by sea goes as non-hazardous.

Product 2 Clearasil Ultra Deep Pore Face Wipes

The main ingredient is Ethanol which is a flammable liquid. The wipe has absorbed the liquid ethanol without any free flowing liquid visible. The product is solid and is readily flammable due to the presence of ethanol. Due to the flammability of the absorbed liquid this is classified under SOLIDS CONTAINING FLAMMABLE LIQUID, N.O.S. UN 3175, Packing Group II.

If we have above two products as cargo by Sea product 1 will go as non –hazardous and product 2 will go as hazardous with dangerous goods declaration, marking, labelling, placarding and other related provisions applicable.

Above details of ingredients and classification are taken from the manufacturer’s website which may be modified by the manufacturer. The writer does not promote any product for their usage or suggest advantage of one product over other but has only given an example that certain products which we use in daily life may be considered as dangerous goods as per transport regulations. To check applicability, limitations and or exemptions for each mode of transport responsible person shall refer the respective regulations.